Improved State of Health Assessment for Lithium-Ion Batteries Based on Electrochemical Impedance Spectroscopy Measurements

##plugins.themes.bootstrap3.article.main##

##plugins.themes.bootstrap3.article.sidebar##

Published Jul 3, 2026
Gabriele Patrizi Fabio Canzanella Lorenzo Ciani

Abstract

Conventionally, battery State of Health (SOH) is defined through the measurement of discharge capacity. However, such approaches are poorly suited for online and in-vehicle applications, as they require full charge/discharge cycles and accurate current integration over long periods. For this reason, indirect health indicators are widely adopted, especially in automotive PHM frameworks. In this context, Electrochemical Impedance Spectroscopy (EIS) has proven to be an effective tool for investigating battery degradation, as it provides detailed insight into internal electrochemical processes. Nevertheless, EIS measurements are strongly influenced by the operating conditions of the tested device, which reduces their practical value under high or variable stress levels. To address these limitations, this work proposes a robust procedure to extract a one-dimensional Health Indicator (HI) from EIS measurements performed after the electric vehicle (EV) charge phase. Instead of relying on full-spectrum fitting or equivalent circuit modeling which are often computationally intensive and difficult to implement online, the proposed method extracts multiple physically meaningful geometrical features directly from Nyquist plots. The features are normalized and evaluated through an adaptive selection process that identifies the most informative ones for degradation tracking and prognostics, ensuring robustness under varying stress conditions. The selected features are then combined through an innovative algorithm to generate a single HI that accurately reflects the battery degradation trend, enabling integration into automotive Battery Management Systems (BMS). To ensure generalizability and repeatability, the approach is validated at different processing stages using a custom dataset of lithium-ion cells tested under highly stressful charge and discharge conditions for a total of 400 cycles.

How to Cite

Patrizi, G., Canzanella, F., & Ciani, L. (2026). Improved State of Health Assessment for Lithium-Ion Batteries Based on Electrochemical Impedance Spectroscopy Measurements. PHM Society European Conference, 9(1), 1–9. https://doi.org/10.36001/phme.2026.v9i1.4884
Abstract 0 | PDF Downloads 0

##plugins.themes.bootstrap3.article.details##

Keywords

Battery, EIS, State of Health

References
Bian, J., Liu, G., Chen, J., Cao, Y., Chen, R., & Qian, Y. (2025). PSO-MLSt-LSTM: Multi-layer stacked ensemble model for lithium-ion battery SOH prediction via multi-feature fusion. Journal of Energy Storage, 125, 116825. doi: https://doi.org/10.1016/j.est.2025.116825

Catelani, M., Ciani, L., Fantacci, R., Patrizi, G., & Picano, B. (2021). Remaining useful life estimation for prognostics of lithium-ion batteries based on recurrent neural network. IEEE Transactions on Instrumentation and Measurement, 70, 1–11. doi: https://doi.org/10.1109/TIM.2021.3111009

Dini, P., Colicelli, A., & Saponara, S. (2024). Review on modeling and SOC/SOH estimation of batteries for automotive applications. Batteries, 10(1), 34. doi: https://doi.org/10.3390/batteries10010034

Dong, M., Li, X., Yang, Z., Chang, Y., Liu, W., Luo, Y., Lei, W., Ren, M., & Zhang, C. (2024). State of health (SOH) assessment for LIBs based on characteristic electrochemical impedance. Journal of Power Sources, 603, 234386. doi: https://doi.org/10.1016/j.jpowsour.2024.234386

Du, X., Meng, J., Amirat, Y., Gao, F., & Benbouzid, M. (2025). Feature selection strategy optimization for lithium-ion battery state of health estimation under impedance uncertainties. Journal of Energy Chemistry, 101, 87–98. doi: https://doi.org/10.1016/j.jechem.2024.09.032

Guo, A. Y., Hou, B. R., Li, C. P., & Xu, D. L. (2024). EIS-based ECM parameter and SOH estimation for LiFePO₄ battery considering SOC effect. In 2024 IEEE 10th International Power Electronics and Motion Control Conference (IPEMC2024-ECCE Asia) (pp. 3362–3368). doi: https://doi.org/10.1109/IPEMC-ECCEAsia60879.2024.10567445

Iurilli, P., Brivio, C., & Wood, V. (2021). On the use of electrochemical impedance spectroscopy to characterize and model the aging phenomena of lithium-ion batteries: A critical review. Journal of Power Sources, 505, 229860. doi: https://doi.org/10.1016/j.jpowsour.2021.229860

Lee, H., Yoo, M. Y., Choi, J.-H., Sung, W., & Heo, J. S. (2024). State-of-charge and state-of-health estimation for Li-ion batteries of hybrid electric vehicles under deep degradation. PHM Society European Conference, 8(1), 10. doi: https://doi.org/10.36001/phme.2024.v8i1.4032

Omakor, J., Miah, M. S., & Chaoui, H. (2024). Battery reliability assessment in electric vehicles: A state-of-the-art. IEEE Access, 12, 77903–77931. doi: https://doi.org/10.1109/ACCESS.2024.3406424

Patrizi, G., Canzanella, F., & Ciani, L. (2025). Towards a novel indirect battery health indicator based on electrochemical impedance spectroscopy for RUL estimation in electric vehicles. In 2025 IEEE International Workshop on Metrology for Automotive (MetroAutomotive) (pp. 139–144). doi: https://doi.org/10.1109/MetroAutomotive64646.2025.11119269

Shan, R., Wang, Y., Guo, S., Cui, Y., Zhao, L., Li, J., & Wang, Z. (2025). From empirical measurements to AI fusion: A holistic review of SOH estimation techniques for lithium-ion batteries in electric and hybrid vehicles. Energies, 18(13), 3542. doi: https://doi.org/10.3390/en18133542

Yang, S., Zhang, C., Jiang, J., Zhang, W., Zhang, L., & Wang, Y. (2021). Review on state-of-health of lithium-ion batteries: Characterizations, estimations and applications. Journal of Cleaner Production, 314, 128015. doi: https://doi.org/10.1016/j.jclepro.2021.128015

Yu, J., Guo, Y., & Zhang, W. (2024). Anomaly detection for charging voltage profiles in battery cells in an energy storage station based on robust principal component analysis. Applied Sciences, 14(17), 7552. doi: https://doi.org/10.3390/app14177552

Zhou, Z., Li, Y., Wang, Q.-G., & Yu, J. (2023). Health indicators identification of lithium-ion battery from electrochemical impedance spectroscopy using geometric analysis. IEEE Transactions on Instrumentation and Measurement, 72, 1–9. doi: https://doi.org/10.1109/TIM.2023.3272401
Section
Technical Papers